a) 

\(n_{MgCl_2}=\dfrac{38}{95}=0,4\left(mol\right)\)

\(n_{CO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: MgCO₃ + 2HCl --> MgCl₂ + CO₂ + H₂O

                0,3<------0,6<------0,3<----0,3

            MgO + 2HCl --> MgCl₂ + H₂O

               0,1<---0,2<------0,1

=> \(\left\{{}\begin{matrix}m_{MgO}=0,1.40=4\left(g\right)\\m_{MgCO_3}=0,3.84=25,2\left(g\right)\end{matrix}\right.\)

b) \(m_{HCl}=\left(0,6+0,2\right).36,5=29,2\left(g\right)\)

=> \(m_{dd.HCl}=\dfrac{29,2.100}{20}=146\left(g\right)\)

Khối lượng sắt:mFe=0,46298*60,5=28 g=>mZn=32,5g

=>nFe=0,5;nZn=0,5

ta có:nCl- =2nFe+2nZn=2 mol =>nHCl=2mol

=>nH2 =1mol.=>V H2=44,8 lit

m muối =m kim loại +m Cl- =60,5 +2*35,5=131,5

131,5 tích nha

PTHH: \(K_2O+2HCl\rightarrow2KCl+H_2O\)

            \(K_2SO_3+2HCl\rightarrow2KCl+SO_2\uparrow+H_2O\)

a) Ta có: \(\left\{{}\begin{matrix}n_{HCl}=\dfrac{200\cdot14,6\%}{36,5}=0,8\left(mol\right)\\n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_3}=0,3\left(mol\right)\\n_{K_2O}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{K_2O}=\dfrac{0,1\cdot94}{0,1\cdot94+0,3\cdot158}\cdot100\%\approx16,55\%\\\%m_{K_2SO_3}=83,45\%\end{matrix}\right.\)

b) Theo các PTHH: \(n_{KCl}=0,8\left(mol\right)\) \(\Rightarrow m_{KCl}=74,5\cdot0,8=59,6\left(g\right)\)

Mặt khác: \(\left\{{}\begin{matrix}m_{hh}=56,8\left(g\right)\\m_{SO_2}=0,3\cdot64=19,2\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{SO_2}=237,6\left(g\right)\)

\(\Rightarrow C\%_{KCl}=\dfrac{59,6}{237,6}\cdot100\%\approx25,1\%\)

Gọi n Fe = a (mol )

       n Mg = b (mol )  (a,b > 0)

--> 56a+24b = 13,2 

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a            2a           a           a

\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

b             2b             b            b

----> a+b=0,35 

Ta có hệ Pt :

\(\left\{{}\begin{matrix}56a+24b=13,2\\a+b=0,35\end{matrix}\right.\)

Giải hệ PT , ta có : 

a= 0,15 

b = 0,2 (mol )

\(V_{HClđủ}=\left(0,15.2+0,2.2\right):0,5=1,4\left(l\right)\)

\(a,m_{Fe}=0,15.56=8,4\left(g\right)\)

\(m_{Mg}=0,2.24=4,8\left(g\right)\)

\(\%m_{Fe}=\dfrac{8,4}{13,2}.100\%\approx63,64\%\)

\(\%m_{Mg}=\dfrac{4,8}{13,2}.100\%\approx36,36\%\)

\(b,m_{FeCl_2}=0,15.127=19,05\left(g\right)\)

\(m_{MgCl_2}=0,2.95=19\left(g\right)\)

\(c,HCl+NaOH\rightarrow NaCl+H_2O\)

    0,2        0,2 

\(m_{NaOH}=\dfrac{100.8}{100}=8\left(g\right)\)

\(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)

\(V_{HCldư}=\dfrac{n}{C_M}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)

\(V_{HCl}=V_{HClđủ}+V_{HCldư}=1,4+0,4=1,8\left(l\right)\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

x            2x        x             x 

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

y          2y             y        y 

\(\left\{{}\begin{matrix}x+y=0,5\\24x+56y=23,2\end{matrix}\right.\)

\(\Leftrightarrow x=0,15;y=0,35\)

\(a,m_{Mg}=0,15.24=3,6\left(g\right)\)

\(m_{Fe}=19,6\left(g\right)\)

\(b,m_{HCl}=\left(0,3+0,7\right).36,5=36,5\left(g\right)\)

\(m_{ddHCl}=1,14.200=228\left(g\right)\)

\(C\%=\dfrac{36,5}{228}.100\%=16\%\)

\(a.n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\\ n_{Mg}=a;n_{Fe}=b\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+56b=23,2\\a+b=0,5\end{matrix}\right.\\ \Rightarrow a=0,15;b=0,35mol\\ m_{Mg}=0,15.24=3,6g\\ m_{Fe}=23,2-3,6=19,6g\\ b.m_{HCl}=\left(0,15+0,35\right).2.36,5=36,5g\\ m_{ddHCl}=1,14.200=228g\\ C_{\%HCl}=\dfrac{36,5}{228}\cdot100=16,01\%\)

Fe+2HCl->FeCl₂+H₂

x---2x-----------x

Mg+2HCl->MgCl₂+H₂

y------2y-----------y

Ta có :

\(\left\{{}\begin{matrix}56x+24y=24\\x+y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,3 mol, y=0,3 mol

=>%m Fe=\(\dfrac{0,3.56}{24}.100\)=70%

=>%m Mg=100-70=30%

=>VHCl=\(\dfrac{0,3.2+0,3.2}{2}\)=0,6l=600ml

b)

 XCl₂+2AgNO₃->2AgCl+X(NO₃)₂

0,6--------------------1,2mol

=>m AgCl=1,2.143,5=172,2g

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